Silyltitanocene and silylzirconocene complexes : intermediates in catalytic coupling of organosilanes
Primary silanes of the type RSiH$ sb3$, where R = phenyl (Ph), benzyl (Bz) and n -hexyl, undergo catalytic dehydrogenative polymerisation in the presence of catalytic amounts of Cp$ sb2$TiMe$ sb2$ (Cp = $ eta sp5$-C$ sb5$H$ sb5)$ to give linear oligomers consisting of about 10 silicon atoms, regardl...
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| Format: | Others |
| Language: | en |
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McGill University
1986
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| Online Access: | http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=72099 |