Theoretical and experimental investigations in chemistry: Part 1- SN2 Reactivity at C-6 in hexopyranosides, Part 2- Polarizability and raman intensities in hydrocarbons
In this thesis, two rather different types of problems were investigated. The first was a case of anomalous reactivity in the area of carbohydrate synthesis. Hexopyranosides having the galacto configuration (i.e. C-4?OR axial) display very low SN2 reactivities towards anionic nucleophiles, wherea...
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| Language: | en_US |
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2005
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| Online Access: | http://hdl.handle.net/1993/118 |