Phosphine-promoted cross-coupling reactions of propargylcopper reagents and alkenyl iodides and the total synthesis of (-)-gloeosporone via nickel-catalyzed epoxide-alkyne reductive macrocyclization

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2007. === Vita. === Includes bibliographical references. === I. Phosphine-Promoted Cross-Coupling Reactions of Propargylcopper Alkenyl Iodides Reagents and Alkenyl Iodides. An electron-rich phosphine additive is critical and...

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Bibliographic Details
Main Author: Trenkle, James D. (James Douglas)
Other Authors: Timothy F. Jamison.
Format: Others
Language:English
Published: Massachusetts Institute of Technology 2007
Subjects:
Online Access:http://hdl.handle.net/1721.1/39582