Functionalized metalloporphyrin catalysts as cytochrome P450 enzyme mimics
The structural and mechanistic similarities between metalloporphyrin (MP) catalysts and the heme-cofactor of cytochrome P450 (CYP) oxygenase enzymes (heme B), have made MPs one of the most viable options for biomimetic catalysis. In heme-monooxygenase enzymes, the amino acid ligate contributes subst...
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| Online Access: | http://hdl.handle.net/2047/D20211237 |