Studies towards Developing Diastereoselective SN1 Reactions of α-Keto Carbocations
Although α-keto carbocations have been demonstrated to be viable intermediates in solvolysis reactions, their applications in synthesis are scarce. These species can be considered to be equivalent to “reversed polarity” enolates and, as such, could be useful for the asymmetric formation of carbon-ca...
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| Language: | en_ca |
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2010
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| Online Access: | http://hdl.handle.net/1807/24246 |