含硫三鐵錯合物[SFe3(CO)9]2-的化性研究與新系列15族-鉻錯合物的合成開發與相關反應探討
博士 === 國立臺灣師範大學 === 化學研究所 === 88 === Abstract 1. S/Fe/CO System The reaction of Na2SO3 with Fe(CO)5/KOH in methanol forms the tetrahedral cluster [Et4N]2[SFe3(CO)9] (1) in good yield. Acidification of 1 with H+ forms the monohydrido cluster [Et4N][SFe3(m-H)(CO)9] and the dih...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2000
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| Online Access: | http://ndltd.ncl.edu.tw/handle/98717449185384533627 |