Synthesis and Related Reactions of Ruthenium Cyclopropenyl and Azirine Complexes

博士 === 國立臺灣大學 === 化學研究所 === 88 === A convenient, high-yield route to [Tp(PPh3)2Ru-C≡C-Ph] (2, Tp = HB(pz)3, pz = pyrazolyl) has been found through the intermediacy of RuCl2(Hpz)2(PPh3)2 (3). This complex is readily obtained on treatment of Ru(PPh3)3Cl2 with 2 equivalents pyrazole in boiling THF. M...

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Bibliographic Details
Main Authors: Yih-Hsing Lo, 羅義興
Other Authors: Ying-Chih Lin
Format: Others
Language:zh-TW
Published: 2000
Online Access:http://ndltd.ncl.edu.tw/handle/23621565731731900398