Chiral Titanium(IV) Complesex and Enantioselective Reduction of Aromatic ketones with Borane

博士 === 國立中興大學 === 化學系 === 89 === In the reactions of TiCl4 with 2,4-pentanedione, Ti(acac)Cl3(THF) 58 and [Ti(acac)Cl2(THF)]2(m-O) 59 were prepared. The x-ray structural analysis was carried out on complex 58. Complex 58 crystallizes in the monoclinic P21/n space group with a = 8.664(1) Å, b = 11....

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Bibliographic Details
Main Authors: Ming-Yuan Shao, 邵明遠
Other Authors: Han-Mou Gau
Format: Others
Language:en_US
Published: 2001
Online Access:http://ndltd.ncl.edu.tw/handle/73225789179815768344