C-C Bond Formation of Terminal alkyne with Alkyl Halide via Rhodium Acetylide Complexes : Synthesis and Related Reactions.
博士 === 國立臺灣大學 === 化學研究所 === 90 === Reactions of various alkyne with Rh(CO)(PPh3)2X, (X = Cl, 2a; Br, 2b; I, 2c) result in formation of a wide variety of rhodium acetylide complexes. Reaction of 2a with terminal alkyne HC≡C(p-C6H4-E), (3a, E = H; 3b, E = NO2; 3c, E = CN; 3d, E = CH3) result in rhodiu...
| Main Authors: | , |
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| Format: | Others |
| Language: | en_US |
| Published: |
2002
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| Online Access: | http://ndltd.ncl.edu.tw/handle/99660869211167194554 |