Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M1(Por1)(L)n, M1 = Ni, Cu , Por1 = (N-m-NSO2C6H4NO2-tpp) ; M2(Por2)(L)n , M2 =Co，Por2 = (N-NCO(o-O)C6H4-tpp)

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