Preparation and Chemical Reactions of Metal Vinylidene Complexes Pending with Olefinic Functionality
博士 === 國立臺灣大學 === 化學研究所 === 97 === The reactivity of a series of cationic metal alkenyl-vinylidene complexes of ruthenium and osmium containing the cyclopentadienyl and phosphine ligand are explored. The methoxyvinylidene complex [Ru]{=C=CHCH(OMe)CH2C(Me)2CH=CH2}[PF6] (7, [Ru] = (η5-C5H5)(PPh3)2Ru)...
Main Authors: | , |
---|---|
Other Authors: | |
Format: | Others |
Language: | en_US |
Published: |
2009
|
Online Access: | http://ndltd.ncl.edu.tw/handle/74081848025597837273 |