Preparation and Chemical Reactions of Metal Vinylidene Complexes Pending with Olefinic Functionality

博士 === 國立臺灣大學 === 化學研究所 === 97 === The reactivity of a series of cationic metal alkenyl-vinylidene complexes of ruthenium and osmium containing the cyclopentadienyl and phosphine ligand are explored. The methoxyvinylidene complex [Ru]{=C=CHCH(OMe)CH2C(Me)2CH=CH2}[PF6] (7, [Ru] = (η5-C5H5)(PPh3)2Ru)...

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Bibliographic Details
Main Authors: Yu-Hao Huang, 黃昱豪
Other Authors: Ying-Chih Lin
Format: Others
Language:en_US
Published: 2009
Online Access:http://ndltd.ncl.edu.tw/handle/74081848025597837273