Syntheses and Reactivities of Ruthenium Complexes Containing a Alkoxybis(pyrazolyl)borate Ligand

碩士 === 臺北市立教育大學 === 自然科學系碩士班 === 99 === Reactions of RuCl2(PPh3)3with K[H2B(pz)2] in methanol and ethanol provide the complexes RuH{κ3-O,N,N'-(RO)2B(pz)2}(PPh3) (R = Me (1)) and RuCl{κ3-O,N,N'-(RO)2B(pz)2}(PPh3)2 (R = Me(2), Et(3)) via pyrazole scrambling. Surprisingly, the complexes of Ru...

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Bibliographic Details
Main Authors: Shu-Kai Chen, 陳書楷
Other Authors: Yih-Hsing Lo
Format: Others
Language:zh-TW
Published: 2011
Online Access:http://ndltd.ncl.edu.tw/handle/90438703245795178612