TiCl4-Mg-CHBr3 Promoted Bromo and Dibromomethylenation of Ketones and Aldehydes; Concise Asymmetric Synthesis of the Epoxycyclohexenone Model Core of Scyphostatin and Isariotin E
博士 === 國立中興大學 === 化學系所 === 100 === In the first chapter, we described CBr2 transfer reaction of CHBr3 promoted Mg-TiCl4 represents an extremely simple, practical, and selective dibromomethylenation of a variety of ketones and aldehydes, especially in enolizable or sterically hindered ketones such as...
Main Authors: | , |
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Other Authors: | |
Format: | Others |
Language: | en_US |
Published: |
2012
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Online Access: | http://ndltd.ncl.edu.tw/handle/60450891763633396181 |