TiCl4-Mg-CHBr3 Promoted Bromo and Dibromomethylenation of Ketones and Aldehydes; Concise Asymmetric Synthesis of the Epoxycyclohexenone Model Core of Scyphostatin and Isariotin E

博士 === 國立中興大學 === 化學系所 === 100 === In the first chapter, we described CBr2 transfer reaction of CHBr3 promoted Mg-TiCl4 represents an extremely simple, practical, and selective dibromomethylenation of a variety of ketones and aldehydes, especially in enolizable or sterically hindered ketones such as...

Full description

Bibliographic Details
Main Authors: Yeshwant Ramchandra Bhorge, 葉栩
Other Authors: Tu-Hsin Yan
Format: Others
Language:en_US
Published: 2012
Online Access:http://ndltd.ncl.edu.tw/handle/60450891763633396181