Synthesis of Ruthenium Formyl Complex and Coupling Reactions between Alkynes and Secondary Amines via Ruthenium Complexes
碩士 === 臺北市立教育大學 === 應用物理暨化學系化學組碩士班 === 100 === The complex Tp(PPh3)(Ph2C=NH)Ru-Cl {Tp = HB(pz)3, pz = pyrazolyl} reacts with propargyl alcohol (HCα≡Cβ-CγH2OH) and results in the formation of the ruthenium carbonyl complex and a formaldehyde via Cα≡Cβ and Cβ-Cγ bonds cleavage. The C=C bond is oxidize...
| Main Authors: | , |
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2012
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| Online Access: | http://ndltd.ncl.edu.tw/handle/74866584347956683960 |