Synthesis of Fluorine-Containing Tetrasubstituted Ethylene Via Two-Step Reactions

碩士 === 國防大學理工學院 === 化學工程碩士班 === 101 === Triethyl 2-fluoro-2-phosphonoacetate (EtO)2P(O)CFHCO2Et, prepared from triethyl phosphite (EtO)3P and ethyl chlorofluoroacetate CFClCO2Et via Michaelis- Arbuzov reaction, reacts with n-butyllithium in THF to give the phosphonate carbanion [(EtO)2P(O)CFCO2Et]-L...

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Bibliographic Details
Main Authors: Ting-Yu Jian, 簡廷宇
Other Authors: Hou-Jen Tsai
Format: Others
Language:zh-TW
Published: 2013
Online Access:http://ndltd.ncl.edu.tw/handle/28173542165571451291