Study on the Olefination of Fluorine-containing Michaelis-Becker reagent
碩士 === 國防大學理工學院 === 化學工程碩士班 === 101 === Esterification of phosphorus trichloride (PCl3) with 2,2,2-trifluoroethanol (CF3CH2OH) gives bis(2,2,2-trifluoroethyl)phosphate ((CF3CH2O)2P(O)H). Treat- ment of (CF3CH2O)2P(O)H with sodium hydride under -42oC gives (CF3CH2O)2P(O)-Na+ carbanion. Reaction of (C...
Main Authors: | , |
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
2013
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Online Access: | http://ndltd.ncl.edu.tw/handle/84514452471866193962 |