I.銠(I)金屬結合掌性配位體催化不對稱1,4-加成在-Nitrostyrenes化合物及應用在3,4-二氫異喹啉和(S)-SKF 38393的形式合成。II.銠(I)金屬結合掌性配位體催化不對稱1,4-加成在-Nitroacrylate化合物。
碩士 === 國立臺灣師範大學 === 化學系 === 101 === Part 1:Chiral diarylnitroethane were prepared from the asymmetric addition of a range of arylboronic acids to -nitrostyrene in the presence of Rh(I) diene complex. This process offers the 1,4-adducts in good yields and excellent enantioselectivities (ee value up...
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2013
|
| Online Access: | http://ndltd.ncl.edu.tw/handle/67728636735364838211 |