含十六族元素(硫、硒、碲)與過渡金屬(鉻、錳、鐵)之團簇化合物的合成與反應探討以及化性與物性研究
碩士 === 國立臺灣師範大學 === 化學系 === 101 === E–Cr (E = S, Se) System The reaction of sulfur powder or SeO2 with Cr(CO)6 in molar ratio of 2: 3 in KOH/MeOH/hexanes solutions at 80 oC formed a selenium-capping trichromium closo-trigonal-bipyramidal (TBP) carbonyl hydride clusters [HE2Cr3(CO)9]3– (E = S, 1a...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2013
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| Online Access: | http://ndltd.ncl.edu.tw/handle/48341133807126520172 |