Spectroscopic Characteristics of {Fe(NO)2}9/10 Four-/Five-/Six-Coordinate Dinitrosyl Iron Complexes (DNICs) and Insight into Redox Sibling of [{Fe(NO)2}9-L]+, [{Fe(NO)2}10-L] and [{Fe(NO)2}10-L−]− DNICs
博士 === 國立清華大學 === 化學系 === 103 === Compared to the tetrahedral {Fe(NO)2}9 dinitrosyliron complexes (DNICs) [(L)2Fe(NO)2]− displaying EPR signal g = 2.03, the newly synthesized six-/five-coordinate {Fe(NO)2}9 DNICs [(TPA)Fe(NO)2][BF4] (1-TPA), [(iPrPDI)Fe(NO)2][BF4] (3-iPrPDI) and [(PyImiS)Fe(NO)2] (5...
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| Format: | Others |
| Language: | en_US |
| Published: |
2015
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| Online Access: | http://ndltd.ncl.edu.tw/handle/15183027702493880021 |