Enantioselective 1,2-Addition of Aryl Boronic acids to α-Diketones using Rh/diene Complexes
碩士 === 國立臺灣師範大學 === 化學系 === 103 === Using 3 mol% of the chiral bicyclo[2.2.1]heptadiene ligand in the Rh(I)-catalyzed enantioselective 1,2-addition of a variety of arylboronic acids 2 to α-diketones 1, with DABCO as the base in the toluene‐water binary solvent system at 60 °C. Afforded the correspon...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2015
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| Online Access: | http://ndltd.ncl.edu.tw/handle/g2ncqk |