Study on Rhodium-Catalyzed Intramolecular Cyclopropanation of Unsaturated α-Diazo-β-ketonitrile Compounds
碩士 === 國立東華大學 === 化學系 === 105 === Abstract Several α-diazo-β-ketonitriles bearing trans-2-allyl-, vinyl- and phenylcycloalkyl groups were synthesized and investigated for intramolecular cyclopropanation. Under the catalysis of Rh2(OAc)4 (1 mol%) in CH2Cl2, the cyclopropanation reactions of the ally...
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| Format: | Others |
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2017
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| Online Access: | http://ndltd.ncl.edu.tw/handle/87397691067055016265 |