Amidophosphine complexes of zirconium and titanium for dinitrogen activation
The preparation and reactivity of zirconium and titanium complexes with the macrocyclic P₂N₂ ligand (where P₂N₂ = PhP(CH₂SiMe₂NSiMe₂CH₂)₂PPh) or the chelating NPN ligand (where NPN = PhP(CH₂SiMe₂NPh)₂) are presented. The zirconium dinitrogen complex ([P₂N₂]Zr)₂(μ-η²: η²-N₂) reacts with (p-methyl...
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| Language: | English |
| Published: |
2010
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| Online Access: | http://hdl.handle.net/2429/18455 |