Remote oxidation of natural products
Remote oxidation at the C-5 position of isobornyl acetate (37) by chromium trioxide in glacial acetic acid/acetic anhydride, and the application of this oxidation to monoterpenes having the bicyclo[2.2.1] heptane framework is described. Subsequent conversion of 5- ketoisobornyl acetate (38) to 5-ke...
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Language: | English |
Published: |
2010
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Online Access: | http://hdl.handle.net/2429/18885 |