Synthesis of chiral ferrocenylphosphine complexes of rhodium (I) and their use as catalysts for homogeneous asymmetric hydrogenation
The present work was directed toward the synthesis of a new chiral catalyst for asymmetric homogeneous hydrogenation. Efficient ways to synthesize the ferrocenylphosphine ligands (R,S)- and (S,R)-⍺-[2-diphenylphosphinoferrocenyl]ethyldimethylamine ((R,S)- and (S,R)-FcNP) and their cationic rhodium c...
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| Language: | English |
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2010
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| Online Access: | http://hdl.handle.net/2429/20726 |