Synthetic routes from camphor to longicamphane and picrotoxane derivatives
Camphor has been functionalized at the C-(8) position by treating (+)-3,3-dibromocamphor with bromine and chlorosulphonic acid. A mechanistic rationalization is proposed for this transformation which accounts for the presence of the minor side products that form during 8- and 9-bromination. (+)-8-Br...
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| Language: | English |
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2010
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| Online Access: | http://hdl.handle.net/2429/22310 |