Thermal rearrangement of functionalized 6-exo-(1-alkenyl)bicyclo\3.1.0]hex-2-enes application to the total synthesis of (+)-sinularene
This thesis describes firstly, a study involving the thermal rearrangement of substituted 6-e̲x̲o̲-(1-alkenyl) bicyclo-[3.1.0]hexenes, and secondly, the application of this type of transformation to a total synthesis of (±)-sinularene (1̲2̲5̲). The 6-e̲x̲o̲-(1-alkenyl)bicyclo[3.1.0]hexenes (1̲8̲7̲,...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/25806 |