Addition-transfer reactions of zirconium alkyne complexes

A unique type of reaction, namely the addition-transfer process, has been developed. This reaction transforms the zirconium alkyne complexes, Cp2Zr(η²-alkyne)(PMe₃), to 2-diphenylphosphino and 2-trimethylstannyl alkenyl zirconium compounds by reaction with Ph₂PCI and Me₃SnCl respectively. In the for...

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Bibliographic Details
Main Author: Mylvaganam, Murugesapillai
Language:English
Published: University of British Columbia 2010
Online Access:http://hdl.handle.net/2429/27602