A photochemical study of crystalline dibenzobarrelene diesters : the di-[pi]-methane photorearrangement in the solid state
The di-π-methane photorearrangement has been investigated for the first time in the solid state. A series of symmetric (-CO₂R₁ = -CO₂R₂) and mixed (-CO₂R₁ ≠CO₂R₂) 11,12-dibenzobarrelene diesters, used as the model substrates, reacted in the solid state with efficiencies that are similar to those obs...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/29105 |