Stereochemistry of the reaction of molecular oxygen with alkyl free radicals
In order to obtain chemical evidence concerning the configuration of free alkyl radicals, 1-(carbo-t-butylperoxy)-cis- and trans-1,4-dimethylcyclohexane and exo- and endo-2-(carbo-t-butylperoxy)-2-methylnorbornane have been synthesized, and their decomposition rates and products determined. The cis...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/37509 |