Mechanism of permanganate oxidation of aliphatic amines
The mechanism of the permanganate oxidation of benzylamine and benzylamine-α-d₂ has been investigated in the pH region 2 to 14. The deuterium isotope effect, kH/kD, was found to be 7-0 from pH 8 to 10.7. The absence of salt effects and the observation that the oxidation rate followed the ionization...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/37656 |