Vibrational spectroscopy of intermediates of carbon-hydrogen bond activation by transition metal oxide cations
Direct, efficient oxidation of alkanes is a long-standing goal of catalysis. Gas phase FeO+ can convert methane to methanol and benzene to phenol under thermal conditions. Two key intermediates of these reactions are the [HO-Fe-R]+ insertion intermediate and Fe+(ROH) (R=CH3 or C6H5) exit channel com...
| Main Author: | |
|---|---|
| Language: | ENG |
| Published: |
ScholarWorks@UMass Amherst
2010
|
| Subjects: | |
| Online Access: | https://scholarworks.umass.edu/dissertations/AAI3427491 |