Lipase catalysed reactions of terpenoids : formation of hemiacetal esters : resolution of cryptone and its transformation to cadinenes

During attempted enzyme-catalysed resolution of sterically hindered secondary alcohols, hemiacetals and their esters were unexpectedly detected. Hemiacetal esters are reactive compounds that decompose to alcohol, aldehyde and acid under ordinary work-up conditions i.e. in contact with water, acid, o...

Full description

Bibliographic Details
Main Author: Isaksson, Dan
Format: Doctoral Thesis
Language:English
Published: KTH, Kemi 2006
Subjects:
Online Access:http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-588
http://nbn-resolving.de/urn:isbn:91-7178-225-7