Lipase catalysed reactions of terpenoids : formation of hemiacetal esters : resolution of cryptone and its transformation to cadinenes
During attempted enzyme-catalysed resolution of sterically hindered secondary alcohols, hemiacetals and their esters were unexpectedly detected. Hemiacetal esters are reactive compounds that decompose to alcohol, aldehyde and acid under ordinary work-up conditions i.e. in contact with water, acid, o...
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Format: | Doctoral Thesis |
Language: | English |
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KTH, Kemi
2006
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Online Access: | http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-588 http://nbn-resolving.de/urn:isbn:91-7178-225-7 |