Asymmetric Intra- and Intermolecular Cyclopropanation by Co(II)- Based Metalloradical Catalysis
Metal-catalyzed cyclopropanation of olefins with diazo reagents has attracted research interest because of its fundamental and practical importance. The resulting cyclopropyl units are recurrent motifs in biologically important molecules and can serve as versatile precursors in organic synthesis. Si...
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Scholar Commons
2012
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Online Access: | http://scholarcommons.usf.edu/etd/4262 http://scholarcommons.usf.edu/cgi/viewcontent.cgi?article=5458&context=etd |