Design and application of N,Nʹ-diamidocarbenes: expanding the constraints of stable carbene chemistry.
Strategic incorporation of carbonyl groups into an N-heterocyclic carbene (NHC) scaffold via rapid and high-yielding methodologies culminating in classical deprotonation methods or the novel reduction of geminal dichlorides afforded stable and relatively electrophilic diamidocarbenes (DACs). Similar...
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| Format: | Others |
| Language: | en |
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2015
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| Online Access: | http://hdl.handle.net/2152/30451 |