Advancing Step-Growth Polymers: Novel Macromolecular Design and Electrostatic Interactions in Polyesters and Polyurethanes
Conventional melt transesterification successfully synthesized high molecular weight segmented copolyesters. The cycloaliphatic monomers 2,2,4,4-tetramethyl-1,3-cyclobutanediol (CBDO) and dimethyl-1,4-cyclohexane dicarboxylate (DMCD) afforded sterically hindered, ester carbonyls in high-Tg polyeste...
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Virginia Tech
2013
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| Online Access: | http://hdl.handle.net/10919/23239 |