Synthesis and Characterization of Multi-Component Polymeric Materials Prepared via Free Radical Polymerization
High molecular weight star-shaped polystyrenes were prepared via the coupling of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) terminated polystyrene oligomers with divinylbenzene (DVB) in m-xylene at 138 °C. Linear polystyrene oligomers (Mn = 19,300 g/mol, Mw/Mn = 1.10) were synthesized in bulk st...
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Virginia Tech
2014
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Online Access: | http://hdl.handle.net/10919/27251 http://scholar.lib.vt.edu/theses/available/etd-04252002-212246/ |