Hydrocarbon Functionalization via a New Free Radical-Based Condensation Reaction

Hydrocarbon Functionalization via a New Free Radical-Based Condensation Reaction

A new free radical chain process for the allylation of hydrocarbons and some other substrates utilizing substituted allyl bromides (R-H + C=C-C-Br -> R-C-C=C + HBr) has been developed. Good to excellent yields were observed in all cases. Kinetic chain measurements and competition...

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Bibliographic Details
Main Author: Sadeghipour, Mitra Jr.
Other Authors: Chemistry
Format: Others
Published: Virginia Tech 2014
Subjects:
Addition
Allylation
Allyl bromide
Alkyl aromatic
Bromine
Condensation
Fragmentation
Free Radical
Hydrocarbon
2-Propanol
Reaction Mechanism
Synthesis
Online Access:http://hdl.handle.net/10919/30627
http://scholar.lib.vt.edu/theses/available/etd-61598-21627/

Internet

http://hdl.handle.net/10919/30627
http://scholar.lib.vt.edu/theses/available/etd-61598-21627/

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