Determination of the relative stereochemistry of adducts resulting from the addition lithium dienolates to Michael acceptors
The addition of the lithium dienolate of ethyl crotonate to 2-cyclopentenone was studied to determine the stereochemical outcome of this Michael addition. Proof of the stereochemistry was provided via the unambiguous synthesis and comparison of ketone 73 from norcamphor 85. === Master of Science
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Format: | Others |
Language: | en |
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Virginia Tech
2014
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Online Access: | http://hdl.handle.net/10919/43137 http://scholar.lib.vt.edu/theses/available/etd-06112009-063224/ |