Labile Ligand Variation in Polyazine-Bridged Ruthenium/Rhodium Supramolecular Complexes Providing New Insight into Solar Hydrogen Production from Water
Mixed-metal supramolecular complexes containing one or two RuII light absorbing subunits coupled through polyazine bridging ligands to a RhIII reactive metal center were prepared for use as photocatalysts for the production of solar H2 fuel from H2O. The electrochemical, photophysical, and photochem...
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Virginia Tech
2015
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| Online Access: | http://hdl.handle.net/10919/64364 |