Study of the oxidative degradation of 2,2,3,4,5-pentaphenyl-3- cyclopentenone by various oxidants ; and, [1,5]-sigmatropic phenyl rearrangements in 2- and/or 5-(p- or m-substituted phenyl)-1,3,4-triphenyl-2,4- cyclopentadien-1-ols: electronic effects at the migration terminus
A Harmnett series comprised of seven 2- and/or 5-(p- or m-substituted phenyl)-1,3,4-triphenyl-2,4-cyclopentadien-l-ols was prepared and the ratio of the two-product mixture resulting from their thermal [1,5]- sigmatropic phenyl rearrangements was determined. In this system phenyl could migrate towar...
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| Format: | Others |
| Language: | en_US |
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Virginia Polytechnic Institute and State University
2018
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| Online Access: | http://hdl.handle.net/10919/82896 |