Synthesis, Kinetic and Catalytic Studies of Manganese Complexes with Corrole and Porphyrin Ligands
High-valent transition metal-oxo intermediates play a significant role in the catalytic cycle of the ubiquitous cytochrome P450 enzymes and in biomimetic catalytic systems. In this work, manganese(III) porphyrin and corrole systems (2) were synthesized and characterized by UV-vis absorbance and 1H-N...
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Format: | Others |
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TopSCHOLAR®
2017
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Online Access: | http://digitalcommons.wku.edu/theses/1949 http://digitalcommons.wku.edu/cgi/viewcontent.cgi?article=2954&context=theses |