Generation and Kinetic Studies of Porphyrin-Manganese(IV)-Oxo Intermediates
High-valent metal-oxo complexes are vital as active oxidants in enzymatic and synthetic catalytic oxidations. Inspired by the ubiquitous cytochrome P450 enzyme, researchers have explored the power of metalloporphyrins to mimic one of Nature’s premier catalytic entities. In this work, four manganese(...
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TopSCHOLAR®
2018
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| Online Access: | https://digitalcommons.wku.edu/theses/3074 |