Synthesis and oxidation of vinyl stannyl sulfides.
The alpha-tin effect in which a C-Sn bond adjacent to a thioether interacts with the sulfur 3p lone pair orbital was found in saturated thioethers and results in a lowering of the oxidation potentials of these compounds. From the electrochemical oxidation potentials found in this study the alpha-tin...
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| Language: | en |
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The University of Arizona.
1996
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| Online Access: | http://hdl.handle.net/10150/187512 |