Photochemical reaction of the 5,7,7,12,14,14-hexamethyl- 1,4,8,11-tetraazacyclotetradecanenickel (II)-y-diazido- 5,7,7,12,14,14-hexamethyl-l,4, 8,11-tetraazacyclotetradecanenickel (II) tetrafluoroborate
Photolysis of methanolic solutions of (Ni(tet-b)N3)2^2 +, containing ammonia, various olefins and ammonium tetrafluoroborate, results in the formation of hydrazine and possibly aziridine derivatives. The data have been interpreted in terms of the formation of a coordinated nitrene. A nitrene interme...
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| Format: | Others |
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DigitalCommons@Robert W. Woodruff Library, Atlanta University Center
1980
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| Online Access: | http://digitalcommons.auctr.edu/dissertations/1213 http://digitalcommons.auctr.edu/cgi/viewcontent.cgi?article=2858&context=dissertations |