Synthesis, structure and chemical studies of cationic M(IV) species where M = Ti, Zr, Hf and Sn

The reactions of the Lewis acid SbCl, with MC14 (M=Ti, Zr, Hf and Sn) have allowed the isolation of the hexachloroantimonate(V) salts [MCl3LJ[SbCl6], where M=Ti, Sn, n=3, L = MeCN and M =Zr, Hf, n=4, L=l,4-dioxane and [TiClL7][SbCl6]3, L = MeCN with full spectroscopic characterisation. Other routes...

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Bibliographic Details
Main Author: Palin, Janet
Published: University of Warwick 1994
Subjects:
546
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.238859