Novel enzyme- and free radical-mediated reactions of oxirane derivatives
The thesis describes the use of various hydrolases in the preparation of enantiomerically enriched epoxyesters. Optically enriched n-butyl 4,5- epoxypentanoate was prepared with a 64% enantiomeric excess via the porcine pancreatic lipase-catalysed hydrolysis of the racemic ester. The hydrolase-catal...
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Loughborough University
1993
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.261133 |