Synthesis and structural studies of N- and O- donor complexes of transition and post-transition metal halides
Trimethylamine reacts with MCl2 (M = Mn, Cd, Cu) to give mono adducts of the type MC12Nme3. Recrystallization of MnC12-Nme3 (1) from the polar solvent acetonitrile yields the anionic complexes [NMe3H] [MnCl3] (II) and [Nme3H]2 [MnCl4Δ] (III) both from the same solution. Similarly CuCl2NMe3 (IV) give...
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University of Warwick
1991
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.303350 |