Water-soluble alkyl phosphine complexes of ruthenium and rhodium : an investigation into their different reactivity in solution

The reaction ofP(CH20H)3 and P(C6HS)(CH20ffll with RuCh in methanol yielded the complexes all trans-[RuCh(P(CH20H)3)2(P(CH20H)2H)2] (1) and all trans-[RuCh(P(4Hs)(CH20H)2h(P(C~s)(CH20H)Hh] (2) respectively. The reaction products were characterised by NMR and IR spectroscopy, X-ray crystallography an...

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Bibliographic Details
Main Author: Higham, Lee
Published: University of East Anglia 2000
Subjects:
546
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327496