Some reactions of acyl cation equivalents with nucleophilic aromatic systems

Trimethyloxonium fluoroborate rapidly reacts with nitriles at elevated temperatures, to afford N-methylnitrilium salts. Subsequent reaction with π-excessive heterocyclic aromatic systems has been shown to give rise to iminium salts in moderate to excellent yields. The related imines may be obtained...

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Bibliographic Details
Main Author: Giles, Robert G.
Published: Loughborough University 1986
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.378128