Stereoselective oxidative cyclisations of 1,5,9-trienes : synthetic studies towards eurylene
A novel synthetic route towards the stereoselective formation of trans-THF rings by permanganate promoted oxidative cyclisation of 1,5-diene precursors was developed. This methodology was applied to 1,5-dienoates and 1,5,9-trienoates to afford trans-THF regions of the natural products, (+)-linalool...
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University of Southampton
2008
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.484954 |